I picked up this hat today while browsing for tea mugs at World Market. (And I found a cute mug with a monkey on it!) The details on the shirt didn't come out all that well in the photo - it has a beautiful pleated collar and some additional pleating on the bodice.
Outfit Details: Shirt, BCBG (Bought at Marshalls). Camisole, JCPenney, Jeans, Reference. Boots, Nine West, Necklace, Dress Barn. Hat, World Market.